Get this from a library comprehensive organometallic chemistry ii 11 main group metal organometallics in organic synthesis vol ed alexander mckillop alexander mackillop. Main group organometallic chemistry 1 introduction organometallic compounds have been known and studied for over 250 years many of these early compounds were prepared directly from the metal by oxidative addition of alkyl halides. The group 2 elements are known to form organometallic compounds of these organomagnesium compounds usually in the form of grignard reagents are widely used in organic chemistry while the other organometallic compounds of this group are largely academic. Main group metal carbon bond formation reaction of metal with organic halogen compounds 2m nrx r nm mx n or r xmx y where x yn o reaction driven by exothermic formation of the metal halide o suitable for synthesis of organometallic compounds of the most electropositive elements. Comprehensive organometallic chemistry ii a review of the literature 1982 1994 volume 10 heteronuclear metal metal bonds 1 synthesis of compounds containing heteronuclear metal metal bonds volume 11 main group metal organometallics in organic synthesis 1 lithium 2 sodium and potassium 3 magnesium
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